Silicate Mineral Structures and the Geological Rock Cycle
Silicate Materials and Mineral Structures
Week 7: Silicate materials contain silicon and oxygen and make up 90% of all minerals. The fundamental building block is the silicon tetrahedron (SiO4), often found in silica (SiO2).
Common Silicate Mineral Groups
- Olivine: A silicate mineral group with isolated tetrahedra, common in ultramafic and mafic rocks.
- Isolated tetrahedra: A silicate structure in which silica tetrahedra do not share oxygen with each other.
- Pyroxene: A silicate mineral group with a single-chain structure.
- Single-chain silicate: A silicate structure in which tetrahedra share oxygen to form chains.
- Amphibole: A silicate mineral group with a double-chain structure; commonly contains OH.
- Double-chain silicate: A silicate structure made of two linked chains of silica tetrahedra.
- Sheet silicate: A silicate structure in which tetrahedra form sheets.
- Mica: A sheet silicate mineral group with one strong direction of cleavage.
- Chlorite: A green hydrous sheet silicate commonly associated with low-grade metamorphic rocks such as greenstone.
- Framework silicate: A silicate structure in which tetrahedra are connected in a three-dimensional framework.
- Quartz: A framework silicate made of silicon and oxygen, with the chemical formula SiO2.
- Feldspar: A framework silicate mineral group that commonly contains aluminum and cations such as sodium, potassium, or calcium.
Structural Units and Bonding
- I-beam: A structural unit in single-chain and double-chain silicate minerals, made of chains of silica tetrahedra facing each other with cations in between. I-beams are relatively strong internally, but bonds between neighboring I-beams are weaker, helping explain cleavage in pyroxene and amphibole.
- T-O-T sheet: A sheet-silicate structure made of one octahedral layer between two tetrahedral layers. The tetrahedral sheets face inward toward the octahedral layer. T-O-T sheets are relatively strong internally, but bonds between neighboring T-O-T sheets are weaker, helping explain why minerals such as mica split into thin sheets.
- Silicon-oxygen-silicon bridge: A connection between two silica tetrahedra through a shared oxygen.
- Non-bridging oxygen: An oxygen in a silica tetrahedron that is not shared with another tetrahedron.
- Polymerization: The degree to which silica tetrahedra are linked together.
Magma and Crystallization Processes
- Silica content: The amount of SiO2 in a mineral, rock, or magma.
- Fractional crystallization: The process in which minerals crystallize from magma at different temperatures, changing the composition of the remaining melt.
- Partial melting: The process in which only part of a rock melts, often producing melt with a different composition from the original rock.
- Mafic magma: Magma with relatively low silica content and higher magnesium and iron content; usually less viscous.
- Felsic magma: Magma with higher silica content; usually more viscous.
- Viscosity: Resistance to flow.
Metamorphic Rocks and Hydrous Minerals
- Hydrous mineral: A mineral that contains water or OH– groups in its structure.
- Greenstone: A low-grade metamorphic rock commonly formed from basalt and containing green hydrous minerals such as chlorite.
- Amphibolite: A metamorphic rock rich in amphibole, commonly formed from basalt or gabbro at a higher metamorphic grade than greenstone.
- Eclogite: A high-pressure metamorphic rock commonly containing garnet and pyroxene.
- Garnet: A dense silicate mineral commonly associated with medium- to high-grade metamorphic rocks.
- Dehydration: A metamorphic reaction in which hydrous minerals break down and release water.
Non-Silicate Mineral Categories
- Non-silicate mineral: Minerals other than silicate minerals.
- Carbonate mineral: A mineral containing the carbonate group, such as calcite or dolomite.
- Calcite: A carbonate mineral with the chemical formula CaCO3.
- Dolomite: A carbonate mineral containing calcium, magnesium, carbon, and oxygen.
- Evaporite mineral: A mineral formed by precipitation from evaporating water.
- Halite: An evaporite mineral with the chemical formula NaCl.
- Metallic mineral: A mineral with metallic luster, commonly rich in metals.
- Ore mineral: A mineral that contains a valuable element that may be economically extracted.
- Magnetite: An iron-rich oxide mineral.
- Hematite: An iron-rich oxide mineral commonly showing a reddish-brown streak.
- Galena: A lead sulfide mineral.
- Sphalerite: A zinc sulfide mineral.
Physical Properties and Identification
- Color: The visible color of a mineral in a hand sample.
- Streak: The color of a mineral in powdered form.
- Streak plate: A plate used to produce a mineral powder for observing streak.
- Luster: The way light reflects from a mineral surface.
- Metallic luster: A shiny, metal-like reflection.
- Vitreous luster: A glassy luster.
- Crystal shape: The external shape of a mineral crystal, influenced by internal crystal structure.
- Cleavage: The tendency of a mineral to break along planes of weakness.
- Weak plane: A plane in a crystal structure where bonds are relatively easier to break.
- Hardness: A mineral’s resistance to scratching.
- Mohs hardness scale: A relative hardness scale from 1 to 10 based on which minerals can scratch other minerals.
- Talc: The softest mineral on the Mohs scale.
- Gypsum: A soft mineral that can be scratched by a fingernail.
- Calcite: A carbonate mineral with a hardness of 3 on the Mohs scale.
- Quartz: A hard mineral with a hardness of 7 on the Mohs scale.
- Diamond: The hardest mineral on the Mohs scale.
- Vickers test: A quantitative hardness test involving indentation by a diamond tip.
The Geological Rock Cycle
- Rock cycle: The set of processes that connect igneous, sedimentary, and metamorphic rocks.
- Igneous rock: Rock formed by the cooling and crystallization of magma or lava.
- Sedimentary rock: Rock formed from sediments, chemical precipitates, or biological materials.
- Metamorphic rock: Rock formed by the solid-state transformation of pre-existing rock under elevated pressure and temperature.
- Parent rock: The original rock before metamorphism.
- Sediment: Loose particles produced by weathering and erosion.
