Ammonia Absorption Tower Design and Diameter Calculations
Ammonia Absorption: 1-inch Intalox Packing
Ammonia is being absorbed in a tower using pure water at 25°C and 1.0 atm absolute pressure. The feed rate is 2000 lb/h and contains 2.5 mole % ammonia in air. The process design specifies a liquid-to-gas mass flow rate ratio of 2:1. Using 50% of the flooding velocity and 1-inch Intalox packing, calculate:
- (i) Pressure drop
- (ii) Gas and liquid flow rates
- (iii) Tower diameter
Solution
Given Data:
- Gas rate (G): 2000 lb/h
- Mole fraction of NH3: 0.025
- Ratio L/G: 2:1
- Packing: 1-inch Intalox packing
- Temperature (T): 25°C (298 K)
- Pressure (P): 1 atm (1.013 bar)
- Operating Velocity: 50% of flooding velocity
Liquid Rate Calculation
L/G = 2
L = 2 × 2000 = 4000 lb/h
The pressure at the tower bottom will be above atmospheric. Since the pressure drop will not be large, we take the properties of air at 1 atm (1.013 bar) and 25°C (298 K).
Average Molecular Weight of Feed Gas
The feed gas consists of 97.5% air and 2.5% NH3:
M = (0.975)(29) + (0.025)(17) = 28.7 g/mol
Gas Density Calculation
ρG = PM / RT
ρG = (1.013)(28.7) / (0.08317)(298)
ρG = 1.17 kg/m³ = 0.0732 lb/ft³
Liquid Properties
Liquid viscosity (μL) is taken as that of water at 25°C: 0.81 cP.
Liquid density (ρL): 1000 kg/m³ = 62.4 lb/ft³
Flow Parameter Calculation
Flv = (L’/G’) (ρG/ρL)0.5
Flv = (4000/2000) (1.17/1000)0.5 = 0.07
Calculation of Column Diameter
Using Strigle’s version chart for 2nd-generation packing:
- μL = 0.81 cP
- Packing factor (Fp) for 1-inch Intalox: 92 per ft
- For Flv = 0.07 and assumed ΔP/L = 0.2 inch water/ft, the capacity parameter is 0.66 (interpolated).
Capacity Parameter Formula:
Cs(Fp)0.5 (μ)0.05 = 0.66
Cs(92)0.5 (0.81)0.05 = 0.66
Cs = 0.0695
Superficial Gas Velocity (usG):
Cs = usG (ρG / (ρL − ρG))0.5
0.0695 = usG ((1.17)/(1000 − 1.17))0.5
usG = 2.029 ft/s = 0.618 m/s
Operating Gas Velocity (uop):
uop = (0.618)(0.5) = 0.309 m/s
Volumetric Gas Flow Rate
Convert 2000 lb/h (907.2 kg/h) into m³/s:
Q = (907.2 kg/h) / (1.17 kg/m³ × 3600 s/h) = 0.21 m³/s
Tower Dimensions
Cross-sectional Area (Ac):
Ac = (0.21 m³/s) / (0.309 m/s) = 0.69 m²
Tower Diameter (Dc):
Dc = (4Ac/π)0.5
Dc = 0.94 m = 3.086 ft ≈ 3 ft
Pressure Drop and Final Flow Rates
Pressure Drop at Flooding:
(ΔP/L)fl = 0.115(Fp)0.7 = (0.115)(92)0.7 = 2.725 inch water/ft
Gas Flow Rate:
ρuopAc = (1.17 kg/m³)(0.309 m/s)(0.69 m²) = 0.249 kg/s = 898.04 kg/h
Water Flow Rate:
(1.4)(898.04 kg/h) = 1257.256 kg/h
Ammonia Absorption: 2-inch Berl Saddles
Ammonia is being absorbed in a packed tower using pure water at 28°C and 1.0 atm pressure. The feed rate is 2500 kg/h and contains 4 mole % ammonia in air. The process design specifies a liquid-to-air mass flow rate ratio of 2:1 and the use of 2-inch Berl saddles.
- (i) Calculate the pressure drop in the packing and air mass velocity at flooding condition.
- (ii) Using 60% of the flooding velocity, calculate the pressure drop, gas and liquid flow rate, and tower diameter.
Solution
Given Data:
- Gas flow rate (G): 2500 kg/h
- Mole fraction of NH3: 0.04
- Liquid to gas ratio (L/G): 2:1
- Packing: 2-inch Berl saddles
- Temperature (T): 28°C (301 K)
- Pressure (P): 1 atm (1.013 bar)
- Operating velocity: 60% flooding velocity
Liquid Flow Rate
L = 2 × 2500 = 5000 kg/h
Average Molecular Weight of Gas Mixture
M = (0.96 × 29) + (0.04 × 17) = 27.84 + 0.68 = 28.52 g/mol
Gas Density
ρG = PM / RT
ρG = (1.013 × 28.52) / (0.08314 × 301) = 1.15 kg/m³
Liquid Properties (Water at 28°C)
ρL = 1000 kg/m³
μL = 0.85 cP
Flow Parameter
Flv = (L/G)(ρG/ρL)0.5
Flv = (5000/2500)(1.15/1000)0.5 = 2(0.00115)0.5 = 0.068
Capacity Parameter and Velocity
Packing factor (Fp) for 2-inch Berl saddles: 40 per ft.
From the generalized pressure drop chart for Flv = 0.068 and assumed ΔP/L = 0.2 inch water/ft:
Capacity parameter = 0.82
Capacity Coefficient:
Cs(Fp)0.5(μL)0.05 = 0.82
Cs(40)0.5(0.85)0.05 = 0.82 ⇒ Cs = 0.128
Flooding Gas Velocity (usG):
Cs = usG(ρG/(ρL − ρG))0.5
0.128 = usG[(1.15)/(1000 − 1.15)]0.5
usG = 3.77 ft/s = 1.15 m/s (superficial gas velocity at flooding)
Operating Gas Velocity (uop):
uop = 0.60 × 1.15 = 0.69 m/s
Tower Dimensions
Volumetric Gas Flow Rate (Q):
Q = 2500 / (1.15 × 3600) = 0.604 m³/s
Cross-sectional Area (Ac):
Ac = 0.604 / 0.69 = 0.875 m²
Tower Diameter (Dc):
Dc = (4 × 0.875 / π)0.5 = 1.06 m ≈ 3.48 ft
Pressure Drop Calculations
At Flooding:
(ΔP/L)f = 0.115(Fp)0.7 = 0.115(40)0.7 = 1.52 inch water/ft
At 60% Flooding:
ΔP/L = (0.60)2 × 1.52 = 0.55 inch water/ft
Final Answers:
- Pressure drop at flooding: 1.52 inch water/ft
- Operating pressure drop: 0.55 inch water/ft
- Flooding gas velocity: 1.15 m/s
- Operating gas velocity: 0.69 m/s
- Gas flow rate: 2500 kg/h
- Liquid flow rate: 5000 kg/h
- Tower diameter: 1.06 m ≈ 3.48 ft
Ammonia Absorption: 1-inch Metal Intalox
Ammonia is being absorbed in a tower using pure water at 25°C and 1.0 atm absolute pressure. The feed rate is 1800 lb/h and contains 4 mole % ammonia in air. The process design specifies a liquid-to-gas mass flow rate ratio of 2:1. Using 1-inch metal Intalox as packing, calculate the pressure drop and gas mass velocity at flooding condition. Also, using 60% of the flooding flow rate, calculate the tower diameter.
Solution
Given Data:
- Gas flow rate (G): 1800 lb/h
- Mole fraction of NH3: 0.04
- Liquid to gas ratio (L/G): 2:1
- Packing: 1-inch metal Intalox
- Temperature (T): 25°C (298 K)
- Pressure (P): 1 atm (1.013 bar)
- Operating velocity: 60% flooding velocity
Liquid Flow Rate
L = 2 × 1800 = 3600 lb/h
Average Molecular Weight and Density
M = (0.96 × 29) + (0.04 × 17) = 28.52 g/mol
ρG = (1.013 × 28.52) / (0.08314 × 298) = 1.17 kg/m³ = 0.073 lb/ft³
Liquid Properties (Water at 25°C)
ρL = 1000 kg/m³
μL = 0.81 cP
Flow Parameter
Flv = (3600/1800)(1.17/1000)0.5 = 2(0.00117)0.5 = 0.068
Capacity and Velocity
Packing factor (Fp) for 1-inch metal Intalox: 92 per ft.
From chart (Flv = 0.068, ΔP/L = 0.2): Capacity parameter = 0.66
Capacity Coefficient:
Cs(92)0.5(0.81)0.05 = 0.66 ⇒ Cs = 0.0695
Flooding Gas Velocity (usG):
0.0695 = usG[(1.17)/(1000 − 1.17)]0.5
usG = 2.03 ft/s = 0.618 m/s
Operating Gas Velocity (uop):
uop = 0.60 × 0.618 = 0.371 m/s
Tower Dimensions
Volumetric Gas Flow Rate (Q):
1800 lb/h = 816.48 kg/h
Q = 816.48 / (1.17 × 3600) = 0.194 m³/s
Cross-sectional Area (Ac):
Ac = 0.194 / 0.371 = 0.523 m²
Tower Diameter (Dc):
Dc = (4 × 0.523 / π)0.5 = 0.816 m ≈ 2.68 ft
Pressure Drop at Flooding
(ΔP/L)f = 0.115(92)0.7 = 2.725 inch water/ft
Final Answers:
- Pressure drop at flooding: 2.725 inch water/ft
- Flooding gas velocity: 0.618 m/s
- Operating gas velocity: 0.371 m/s
- Tower diameter: 0.816 m ≈ 2.68 ft
Ammonia Absorption: 1-inch Intalox at 3.5% NH3
Ammonia is being absorbed in a tower using pure water at 25°C and 1.0 atm absolute pressure. The feed rate is 2100 lb/h and contains 3.5 mole % ammonia in air. The process design specifies a liquid-to-gas mass flow rate ratio of 2.2:1. Using 60% of flooding and 1-inch Intalox packing, calculate:
- (i) Pressure drop
- (ii) Gas and liquid flow rates
- (iii) Tower diameter
Solution
Given Data:
- Gas flow rate (G): 2100 lb/h
- Mole fraction of NH3: 0.035
- Liquid to gas ratio (L/G): 2.2:1
- Packing: 1-inch Intalox
- Temperature (T): 25°C (298 K)
- Pressure (P): 1 atm (1.013 bar)
- Operating velocity: 60% flooding velocity
Liquid Flow Rate
L = 2.2 × 2100 = 4620 lb/h
Average Molecular Weight and Density
M = (0.965 × 29) + (0.035 × 17) = 27.985 + 0.595 = 28.58 g/mol
ρG = (1.013 × 28.58) / (0.08314 × 298) = 1.17 kg/m³ = 0.073 lb/ft³
Liquid Properties (Water at 25°C)
ρL = 1000 kg/m³
μL = 0.81 cP
Flow Parameter
Flv = (4620/2100)(1.17/1000)0.5 = 2.2(0.00117)0.5 = 0.075
Capacity and Velocity
Packing factor (Fp) for 1-inch Intalox: 92 per ft.
From chart (Flv = 0.075, ΔP/L = 0.2): Capacity parameter = 0.67
Capacity Coefficient:
Cs(92)0.5(0.81)0.05 = 0.67 ⇒ Cs = 0.0705
Flooding Gas Velocity (usG):
0.0705 = usG[(1.17)/(1000 − 1.17)]0.5
usG = 2.06 ft/s = 0.628 m/s
Operating Gas Velocity (uop):
uop = 0.60 × 0.628 = 0.377 m/s
Tower Dimensions
Volumetric Gas Flow Rate (Q):
2100 lb/h = 952.56 kg/h
Q = 952.56 / (1.17 × 3600) = 0.226 m³/s
Cross-sectional Area (Ac):
Ac = 0.226 / 0.377 = 0.60 m²
Tower Diameter (Dc):
Dc = (4 × 0.60 / π)0.5 = 0.874 m ≈ 2.87 ft
Pressure Drop Calculations
At Flooding:
(ΔP/L)f = 0.115(92)0.7 = 2.725 inch water/ft
Operating Pressure Drop (60% Flooding):
ΔP/L = (0.60)2 × 2.725 = 0.981 inch water/ft
Final Answers:
- Pressure drop: 0.981 inch water/ft packed height
- Flooding gas velocity: 0.628 m/s
- Operating gas velocity: 0.377 m/s
- Gas flow rate: 2100 lb/h (952.56 kg/h)
- Liquid flow rate: 4620 lb/h (2095.63 kg/h)
- Tower diameter: 0.874 m ≈ 2.87 ft
